The Action of Sodium Ethoxide in Absolute Ethanol on Epimeric DL-2-Benzamidocyclohexyl p-Toluenesulfonates
Tanezo Taguchi, Masaharu Kojima
, J. Am. Chem. Soc. 1959, 81, 16, 4316–4318
Sodium ethoxide treatment in absolute ethanol led to the formation of various products, including meso-cis-4-cyclohexanoneoxazoline, trans-4,5-cyclohexenimine, and other intermediate and final compounds. The researchers propose a mechanism explaining these transformations. This study provides insight into the reactivity of benzamidocyclohexyl p-toluenesulfonates with sodium ethoxide, revealing the structural influences on reaction pathways and products.
Sodium ethoxide as an environmentally benign and cost-effective catalyst for chemical depolymerization of post-consumer PET waste
Saqib Javed, Dennis Ropela and Dieter Vogt
, Green Chemistry, Issue 4, 2023
Here, we present our work on the glycolytic depolymerization of post-consumer PET waste using sodium ethoxide (EtONa) as a low-cost catalyst. In order to optimize the reaction in terms of PET conversion and BHET yield, response surface methodology (RSM) based on the Box–Behnken design was applied for the reaction temperature (160–190 °C), the molar ratio of PET : EtONa (50–150), the molar ratio of ethylene glycol to PET (EG : PET) (3–7), the reaction time (2–6 h) and the PET particle size (0.25–1 mm).
Characterization of new Co(II) complexes and photographic monitoring for their toxic impact on breast cancer cells according to simulation study
Shah, Reem,Habeebullah, Turki M.,Saad, Fawaz,Althagafi, Ismail,Al-dawood, Aisha Y.,Al-Solimy, Amerah M.,Al-Ahmed, Zehba A.,Al-Zahrani, Fatimah,Farghaly, Thoraya A.,El-Metwaly, Nashwa
, (2020)
Five new nitrogen-rich ligands (thioanhy...
Synthesis of new polysubstituted (pyrazoles, pyrimidines and quinolines) five and six-membered heterocycles: Reaction of α,α-dioxoketene dithioacetals with nucleophiles
Ebraheem,Lokanatha Rai,Kudva.n,Bahjat
, p. 3486 - 3492 (2010)
A novel synthesis of polysubstituted pyr...
Iron(ii) complexes of 2,6-di(1H-pyrazol-3-yl)-pyridine derivatives with hydrogen bonding and sterically bulky substituents
Roberts, Thomas D.,Little, Marc A.,Kershaw Cook, Laurence J.,Halcrow, Malcolm A.
, p. 7577 - 7588 (2014)
Syntheses of 2,6-di(5-aminopyrazol-3-yl)...
Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands
Saiki, Ryo,Miyamoto, Haruka,Shiga, Takuya,Oshio, Hiroki,Sagayama, Hajime,Kumai, Reiji,Newton, Graham N.
, p. 3231 - 3236 (2019)
Three mononuclear iron(ii) complexes of ...
Synthesis and characterization of new 5,5′-dimethyl- and 5,5′-diphenylhydantoin-conjugated hemorphin derivatives designed as potential anticonvulsant agents
Georgieva, Stela,Peneva, Petia,Rangelov, Miroslav,Tchekalarova, Jana,Todorov, Petar,Todorova, Nadezhda
, p. 2198 - 2217 (2022/02/16)
Herein, the synthesis and characterizati...
